You can add your own by creating it in Engine/Documentation/Source/Shared/Types/YourClass/YourClass.INT.udn
The editor will automatically detect it and show you the ctrl+alt option.
You can learn the syntax by reading the existing documentation files.
Let me know if this is what you were looking for and mark the answer as correct.
This will also work on a project and plugin level as well. You simply need to follow the same folder structure as what is in the Engine folder. You just need to add : “Documentation/Source/Shared/Types/etc…” folder underneath your base project or plugin folder and the engine will pick it up.