So I noticed the two sliders controlling brightness/saturation are a different hue from the selected color on the radial picker. In the above screenshot I have a light orange, yet the sliders indicate I have a hot red selected.
Rather annoying if you want to see what the affects on the color would be over a range of values on the sliders. Right now I more or less have to blindly tweak the colors.
This screenshot was taken from the Material editor, with the color picker for a VectorParameter.