Movie Render Queue, Post Process and Antialiasing

Hey, I am new to unreal and the Post Process Volumes and MRQ CVARS have me confused.

When I am rendering a scene using movie Render Queue is there a hierarchy on what takes effect between CVARS, Post Process Volumes and camera Post Process?
Do I need a PPV in order for certain settings to work? Like, If I want raytracing in the final gather (and disable it in editor to save fps) does a CVAR suffice or does it need to be set in a PPV in the scene?

I am also confused with some settings regarding AA:
Theres Temporal And Spatial Sample Counts and there is AA method. So if I override AA method to none and use Temporal Samples is it using Temporal AA?