What's the easiest way to make curved 90 degree walls?

Actually, bsp shouldnt be used for final products.
its meant to be used as a blocking out tool, and later be replaced with static meshes made in an external 3d program like blender (free) or 3dsmax, maya, zbrush, modo, etc.

So even though Steve’s reply is correct, I highly suggest to not use bsp for this. (EVER)